Show Summary Details
The one-stop-shop for nano science.

# nano Online

More options …

## Search

Search publication

## Background

Carbon-based materials are among the most promising objects of modern nanotechnology. Carbyne is the linear allotrope of carbon. To date, carbyne, as an object of research, leaves behind graphene by the number of works, due to its unique physical, mechanical, and chemical properties [1-4], as well as due to promising applications [5-10]. The possibility of realization of these unusual functional properties is significantly depending on the strength and elasticity of carbyne. Moreover, obtaining of carbyne by unraveling of nanotubes or graphene sheets is governed by its mechanical properties [5,6,10,11]. Therefore, recently, quite a lot of works on the problem of the strength and stability of monatomic carbon chains appeared [12-17]. However, until now, the strength of carbyne was evaluated by the results of ab initio modeling of tension of monatomic carbon chains. Only recently, the first experimental data on in situ determination of the tensile strength of carbyne by high-field method have been published [18,19]. An ultra-high ultimate level of strength of these chains, which at T = 5 K exceeds 270 GPa, was ascertained [19]. This is more than twice higher than the experimental strength of graphene which is equal to 130 GPa [20]. Despite the considerable interest in the carbyne, information about its mechanical properties is scattered in specific works that does not allow obtaining complete representation about these properties. This work is addressed to a brief description of the experimental data obtained by measuring of strength of carbyne, as well as to the results of the molecular dynamics and ab initio modeling of tension of monatomic carbon chains of finite length.

## Methods

The experiments were carried out in an ultra-high-vacuum two-chamber field emission microscope (FEM) with needle-shaped specimens cooled to 4.2 and 77 K. Field ion images were formed by using helium atoms under a pressure of 10−3 Pa; the residual gas pressure was about 10−7 Pa. To use the FEM in the field and electron modes, a constant positive operating voltage of 1 to 20 kV, a varying voltage of amplitude 2 to 5 kV, and frequency of 50 Hz was supplied to carbon tips. The application of a positive voltage ensured the realization of the ion mode. The ratio of positive and negative voltages supplied to the specimen was in the interval from 8 to 14. The amplitude of negative voltage was sufficient for creating on the tip surface a field strength corresponding to an electron current in the interval 10−9 to 10−6 A. A microchannel amplifier of image brightness allowed the use of such low currents to reduce the intensity of ion bombardment of the tip surface during the flow of the field electron current in the electron mode. Carbon specimens with radii of 20 to 50 nm at the top were formed by electrochemical etching in 1 N aqueous sodium hydroxide aqueous solution with an AC voltage of 5 to 8 V from carbon polyacrylonitrile fibers. After placement in the FEM, the carbon tips were cleaned in situ by the methods of field desorption and by low-temperature field evaporation until a mesoscopically regular surface was formed. During this high-field forming, self-standing carbyne chains of different lengths with densities in the range of 1015 to 1016 m−2 are produced at the surface of the carbon specimen as a result of high-field unraveling [21,22]. Details of the experimental procedure, including in situ preparation of carbyne chains anchored on top of a parabolic carbon tip, are described in details elsewhere [19,21,23]. During the high-field treatment, initially sharp carbon tips were blunted up to radii of 200 to 1,000 nm. This process of formation of a ‘hairy’ carbon surface is accompanied by the destruction of a large number of carbyne chains under mechanical stresses generated by a high electric field. The field strength on the top of carbyne chains was determined using the known threshold value for the ionization of helium atoms (22 V/nm) [24]. The operation voltage was measured in these experiments with ±0.1% precision. The image magnification of the field ion microscope M is proportional to the ratio of the distance screen-object under study R and the radius of curvature of the end cap of the carbyne chain ρ:$M\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}R/\beta \rho .$1

There, β is the geometrical image compression factor due to deviation of the shape of the specimen configuration from spherical [21]. For the paraxial trajectories of ions and electrons in a field emission microscope, the compression factor is a universal function of the ratio r 0/L:$\beta \phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}\xi {\left({r}_{0}/L\right)}^{1/2},$2

where ξ is a dimensionless constant equal to 1.145 ± 0.033 which is independent of the carbyne length and the tips’ radius.

For determination of the chain length L, the field-electron technique was applied [1]. It is based on experimental finding the compression factor β of field-electron images of the carbyne chains and determination of the radius r 0 of the carbon tips:$L\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}{r}_{0}{\left(\xi /\beta \right)}^{2},$3

The surface density of ponderomotive forces at the apex of a carbyne chain was determined as:$\sigma \phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}\frac{{\epsilon }_{0}{F}_{\mathrm{e}\mathrm{s}}}{2},$4where ε 0 is the electric constant and F es is the field strength on the effective electric surface at the carbyne apex at operative voltage.

Along with the experimental determination of the strength of carbyne, the work presents molecular dynamics (MD) simulation of the formation of monatomic carbon chains by pulling it out of the graphene sheet. Model of monolayers of carbon atoms included 44 of the interacting atoms and 30 boundary (edge) atoms. Boundary (edge) atoms are held in position of the lattice nodes. Such a model is a stable relatively homogeneous deformation and artifactual phase transformations. In the calculations, we used the fact that the electric forces which create axial tension are localized on top of the carbon chain. In mesoscopic electric field, induced charge is really localized at the top of a linear chain. Consequently, the mechanical strength of the electric field is localized at the top of nanowires. In our calculations, the axial mechanical load varied in the range 7 to 9 nN.

For the analysis of atomism of deformation and break of a monatomic chain, ab initio calculations were employed. The number of atoms in the carbyne was varied from 2 to 13. Full energies of chains were calculated by the pseudo-potential method (software Quantum-ESPRESSO (QE) [25]). This method was applied for modeling the mechanical properties of the chains. Pseudo-potentials for carbon were generated according to the scheme Vanderbilt ultrasoft using the package Vanderbilt code version 7.3.4 [26]. To determine the accuracy of the calculation of the total energies of carbon chains, test calculations for infinite chains with the polyyne and cumulene were performed. Interatomic distances and total energies, consistent with the results of the work [27], were obtained. The value of the cutoff energy is E cut = 450 eV.

## Results and discussion

Experimental determination of the tensile strength of carbyne was executed at a temperature of 77 K. As was shown in [19], idea of the experiment is that the electric potential was raised to the critical level, at which the non-activated forming of the surface of the parabolic tip as a result of the impact of the electric field forces occurred. Formation of a ‘hairy’ carbon surface comes simultaneously with the destruction of some number of carbyne chains under mechanical stresses generated by a high electric field. At reached constant electric potential, these processes of formation and fracture of carbyne chains stop for 2 to 5 s. On lowering the electrical potential, reducing of the field strength takes place and, as a consequence, decreasing in the intensity of ionization above the tops of the chains. Below the threshold potential, the ionization process is completely stopped. At certain value of potential, close to the threshold, only a few longest carbyne chains observed as bright spots contribute to the formation of ion-microscope image (see Figure 1). In this experiment, the threshold potential was V 0 = 590 V, and the maximum potential at the high-fild test reached V max = 810 V. The ratio V max/V 0 in this experiment was equal to 1.37.

Figure 1

Ion microscope image of carbyne chains at a voltage of 590 V. The bright spots correspond to the edge atoms of carbon chains produced during a high-field treatment.

Observation of such chains indicates that they survived and not destroyed at the maximum value of electric field strength, which according to Equation 4, corresponds to mechanical stress of 251 GPa. This strength value was measured at 77 K and it is 7% lower than the strength of 270 GPa previously obtained at a lower temperature 5 K [19]. Influence of local force fluctuation due to the thermal vibration of atoms in carbyne chains is one of the reasons for such difference. The distribution of carbyne chain lengths was determined by the field-electron technique using the values of compression factor and the radius r 0 of the carbon tips. As the statistical analysis showed, the distribution of the carbyne chain length directly calculated from Equation 3 has a mean value of 3.5 nm, with a variance of 1.8 nm.

To analyze the unraveling process, molecular dynamics simulation of the carbon chain elongation of the graphene sheet at a temperature of 77 K was carried out under conditions of constant values of the applied force. Figure 2 illustrates the process of formation of an isolated linear carbon chain under the influence of mechanical forces of the electric field by unraveling the two-dimensional atomic network on the edge of a graphene monolayer. Molecular dynamics simulation has shown that the linear chains are formed and elongated by breaking bonds of the atoms of the chain with the surface of the graphene sheet (contact atomic bond #1 in Figure 2a). Figure 2 exhibits the successive stages of unraveling the graphene under the influence of an electric field producing mechanical load 7.82 nN, resulting in elongation of the chain. Configurations at the initial time (a) and after 6.4 × 10−14 s (b) and 9.6 × 10−14 s (c) are shown.

Figure 2

Unraveling of monolayer graphene with formation and elongation of carbyne chains under tensile forces close to theoretical strength. Configurations at the initial time (a) and after 6.4 × 10−14 s (b) and 9.6 × 10−14 s (c).

As follows from these results, the unraveling force in the interval was equal to 7.85 ± 0.05 nN and characterized strength of atomic bonds at the point of it applying to a graphene layer. If the effective diameter of the chain is 0.2 nm [23], then the value of tensile stress 250 ± 2 GPa corresponds to this value of unraveling force. This agrees well with the experimentally measured value of the critical stress 251 GPa. It means that in the experiment, the bond strength between the chain and the graphene sheet is actually measured, and the strength of the bonds within a chain should be higher. To determine this strength, ab initio modeling of tension of monatomic carbon chains of different lengths was executed (Figure 3).

Figure 3

Force F dependence on strain e for whole chain with odd (a) and even (b) number of atoms. Fc is the critical stresses for instability of the chains; k Y is the coefficient of elasticity of the chain; N is the number of atoms in carbyne.

By the results of ab initio calculations of chain tension, dependence of tensile force F on the value of total chain strain e was built (Figure 3). The force acting on the edge atom was calculated as:$F\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}\frac{dE}{da},$5

where E is the total electron energy and a is the current distances between the first and second atoms in a chain (length of edge bond).

True strain of the whole chain, е, was estimated as:$e\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}1\mathrm{n}\left(\frac{l}{{l}_{0}}\right),$6

where l 0 and l are the initial and current chain lengths.

The values of chain strength, F c, were determined as maximum value of the force at the moment of a chain instability. Values of the coefficient of elasticity (stiffness) k Y and of the elastic modulus Y were calculated as:${k}_{Y}\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}\frac{dE}{de}|e=0$7 $Y\phantom{\rule{0.5em}{0ex}}=\phantom{\rule{0.5em}{0ex}}\frac{{k}_{Y}}{S}$8

where S is the effective cross-sectional area of the chain, through which the force interaction between the atoms in the chain is transmitted. In this work, as well as in [23], the effective value of the diameter of the chain was assumed to be equal 0.2 nm.

According to the results of ab initio simulations, breaking of the chain occurs at edge atomic bond, i.e., the edge atom comes off. It means that the magnitude of strength of the whole chain is determined by the strength of edge bond. The value of this strength depends both on the total number of atoms in the chain and on whether it is odd or even number. In accordance with the obtained results, the strength of chains with an odd number of atoms is higher in comparison with the strength of ‘even’ chains. Carbyne, containing five atoms, has a maximum strength F c = 13.09 nN. Increasing in the number of atoms in the chains gives rise to an increase in the stiffness of the chain, k Y. Starting from the number of atoms N ≥ 12, the strength becomes independent of the chain length and reaches 12.35 nN. According to the data given in [15,17], the strength of the infinite chain is 9.30 to 11.70 and 12.16 nN, respectively (Figure 4).

Figure 4

The effect of the number of atoms in carbyne on its strength, F c, and elasticity, k Y (Y).

As it was noted above, the average length of monatomic chains produced at the surface of the carbon specimen is equal to 3.5 nm. A chain of such length should contain about 28 atoms. In accordance with the results of ab initio calculations, the strength of such a chain should be ≈ 12.35 nN (393 GPa), which is 1.46 to 1.56 times higher than experimentally measured strengths of 270 (5 K) and 251 (77 K) of the contact atomic bond between the chain and the graphene.

## Conclusions

Based on the results of our study, the following conclusions can be made:

1. Carbyne is the strongest material in the world. Experimental estimation of its strength gives the values 270 GPа (at 5 K) and 251 GPa (at 77 K). This is more than two times higher than the strength of graphene (130 GPа).

2. For carbyne of length approximately 1,36 nm, ab initio-calculated value equals 393 GPа (at 0 K). Such a significant difference (from 1.46 to 1.56 times) between the experimental and ab initio values of strength is due to the fact that in the experiment, the strength of contact bond between the chain and the graphene sheet is measured, and ab initio calculations gives the strength of atomic bonds in the chain itself. It means that these experimental values should be considered as a lower bound for the strength of carbyne.

3. Mechanical properties of carbyne containing more than 4 and less than 12 atoms are governed by the scale and ‘even-odd’ effects:

• ‘Even-odd’ effect manifests itself in the fact that carbynes with an odd number of atoms have the greater values of the strength.

• Scale effect lies in growth of modulus of elasticity of chain growth. The strength of ‘even’ carbynes increases monotonically, and the strength of ‘odd’ ones varies non-monotonically. Carbynes containing five atoms have the highest strength which equals 13.09 nN (417 GPa).

4. When the number of atoms in the carbyne exceeds 12, its mechanical properties become independent of the number of atoms and its parity. Strength of such carbyne is ≈ 12.35 nN (393 GPa) (at 0 K), the coefficient of elasticity - k Y = 145.40 nN, and elastic modulus - Y = 4631 GPa.

## Footnotes

• Competing interests The authors declare that they have no competing interests.

• Authors’ contributions SK put tasks and planned investigations. IM and TM performed the MD calculations. ES fulfilled the FIM study. АТ and YuM executed ab initio calculations. NS processed the experimental evidence. All authors analyzed the results and participated in the preparation of the manuscript. All authors read and approved the final manuscript.

• Authors’ information SK is a doctor of sciences in physics and mathematics, professor, head of department of materials strength and fracture physics, and highly qualified specialist in multi-scale approach to strength and reliability of materials.IM is a doctor of sciences in physics and mathematics, professor, leading researcher, and known scientist in the field of high-resolution emission microscopy and high-field technology in Ukraine.TM is a doctor of sciences in physics and mathematics, senior researcher, leading researcher, and known scientist in the field of high-resolution emission microscopy and in computational solid state physics.ES is a Ph.D. degree holder in physics and mathematics, senior researcher, and scientist in the field of structure and mechanical properties of metals and carbon materials.AT is a Ph.D. degree holder in physics and mathematics, senior researcher, and eminently qualified expert in computational solid state physics.NS is a Ph.D. degree holder in physics and mathematics, senior researcher, and specialist in statistical modeling of structure and properties of solids.YuM is a Ph.D. degree holder in physics and mathematics, senior researcher, and specialist in computational solid state physics.

## Acknowledgements

The authors gratefully acknowledge the financial support from Project # 15/14-Н Program ‘Nanosystems, Nanomaterials and Nanotechnologies’ of NAS of Ukraine.

## References

• 1.

Lou, L; Nordlander, P; Smalley, RE: Fullerene nanotubes in electric fields, Phys Rev B, 1995, 52, S. 1429Crossref

• 2.

Ravagnan, L; Manini, N; Cinquanta, E; Onida, G; Sangalli, D; Motta, C: Effect of axial torsion on Sp carbon atomic wires, Phys Rev Lett, 2009, 102, S. 245502

• 3.

Cinquanta, E; Ravagnan, L; Castelli, IE; Cataldo, F; Manini, N; Onida, G: Vibrational characterization of dinaphthylpolyynes: a model system for the study of end-capped sp carbon chains, J Chem Phys, 2011, 135, S. 194501

• 4.

Rinzler, G; Hafner, JH; Nikolaev, P; Lou, L; Kim, SG; Tomanek, D: Unraveling nanotubes: field emission from an atomic wire, Science, 1995, 269, S. 1550

• 5.

Durgun, EE; Senger, RT; Mehrez, H; Dag, S; Ciraci, S: Nanospintronic properties of carbon-cobalt atomic chains, Europhys Lett, 2006, 73, S. 642Crossref

• 6.

Wang, Y; Ning, X-J; Lin, Z-Z; Li, P; Zhuang, J: Preparation of long monatomic carbon chains: molecular dynamics studies, Phys Rev B, 2007, 76, S. 165423Crossref

• 7.

Erdogan, E; Popov, I; Rocha, CG; Cuniberti, G; Roche, S; Seifert, G: Engineering carbon chains from mechanically stretched graphene-based materials, Phys Rev, 2011, 83, S. 041401(R)Crossref

• 8.

Lang, ND; Avouris, P: Oscillatory conductance of carbon-atom wires, Phys Rev Lett, 1998, 81, S. 3515–8Crossref

• 9.

Yazdani, D; Eigler, M; Lang, N: Off-resonance conduction through atomic wires, Science, 1996, 272, S. 1921–4

• 10.

Ragab, T; Basaran, C: The unravelling of open-ended single walled carbon nanotubes using molecular dynamics simulations, J Electron Packag, 2011, 133, 2, S. 020903Crossref

• 11.

Ataca, C; Ciraci, S: Perpendicular growth of carbon chains on graphene from first-principles, Phys Rev B, 2011, 83, S. 235417Crossref

• 12.

Kavan, L; Hlavatý, J; Kastner, J; Kuzmany, H: Electrochemical carbyne from perfluorinated hydrocarbons: synthesis and stability studied by Raman scattering, Carbon, 1995, 33, S. 1321–9Crossref

• 13.

Casari, CS; Li Bassi, A; Ravagnan, L; Siviero, F; Lenardi, C; Piseri, P: Chemical and thermal stability of carbyne-like structures in cluster-assembled carbon films, Phys Rev B, 2004, 69, S. 075422Crossref

• 14.

Jin, C; Lan, H; Peng, L; Suenaga, K; Iijima, S: Deriving carbon atomic chains from graphene, Phys Rev Lett, 2009, 102, S. 205501

• 15.

Liu, M; Artyukhov, VI; Hoonkyung, L; Fangbo, X; Yakobson, BI: Carbyne from first principles: chain of C atoms, a nanorod or a nanorope, ACS Nano, 2013, 7, 11, S. 10075–82

• 16.

Castelli, IE; Salvestrini, P; Manini, N: Mechanical properties of carbynes investigated by ab initio total-energy calculations, Phys Rev B, 2012, 85, S. 214110Crossref

• 17.

Chen, M; Fan-Xin, M; Xi, C; Xi-Jing, N: Tuning the electronic and optical properties of monatomic carbon chains, Carbon, 2014, 68, S. 487Crossref

• 18.

Kotrechko, SA; Mazilov, AA; Mazilova, TI; Sadanov, EV; Mikhailovskij, IM: Experimental determination of the mechanical strength of monatomic carbon chains, Tech Phys Lett, 2012, 38, S. 132Crossref

• 19.

Mikhailovskij, IM; Sadanov, EV; Kotrechko, SA; Ksenofontov, VA; Mazilova, TI: Measurement of the inherent strength of carbon atomic chains, Phys Rev, 2013, B 87, S. 045410Crossref

• 20.

Lee, C; Wei, X; Kysar, JW; Hone, J: Measurement of the elastic properties and intrinsic strength of monolayer graphene, Science, 2008, 321, S. 385–8

• 21.

Mazilova, TI; Mikhailovskij, IM; Ksenofontov, VA; Sadanov, EV: Field-ion microscopy of quantum oscillations of linear carbon atomic chains, Nano Lett, 2009, 9, S. 774–8

• 22.

Mikhailovskij, IM; Sadanov, EV; Mazilova, TI: Sattler, K (Hrsg.): Carbon atomic chains, Fundamental of picosience, 2013, Boca Raton, Taylor & Francis, S. 505–28

• 23.

Mazilova, TI; Kotrechko, S; Sadanov, EV; Ksenofontov, VA; Mikhailovskij, IM: High-field formation of linear carbon chains and atomic clusters, Int J Nanosci, 2010, 9, S. 151–7Crossref

• 24.

Miller, MK; Cerezo, A; Heatherington, MG; Smith, GDW: Atom probe field ion microscopy, 1996, Oxford, Clarendon

• 25.

Giannozzi, P; Baroni, S; Bonini, N; Calandra, M; Car, R; Cavazzoni, C: QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials, J Phys Condens Matter, 2009, 21, S. 395502

• 26.

Garrity, KF; Bennett, JW; Rabe, KM; Vanderbilt, D: Pseudopotentials for high-throughput DFT calculations, Comput Mater Sci, 2014, 81, S. 446Crossref

• 27.

Cahangirov, S; Topsaka, M; Ciraci, S: Long-range interactions in carbon atomic chains, Phys Rev B, 2010, 82, S. 195444Crossref